Sorry, I meant to say phosphate-free coolant/anti freeze, not zinc. ( I was thinking about the zddp additive to engine oil which was largely discontinued in the 90s as zinc was found to be somewhat harmful to newer aluminum engines, and catalytic converters as well.. although there’s still a lot of debate on that topic, and some top oil brands still put zddp in their oils ). But phosphate free coolant is the clear choice for optimum protection of radiators, and I believe the orange color was developed primarily to differentiate phosphate free coolants from the classic green ones.