Looking if they are groved wil give you an indication , but on the other hand , in my believe it has never been an issue that pads have little groves , the reason for the chain to fail , is because the pads over time become brittle and start falling appart , when that happens the pads at one point wil be thorn off and end up between sprocket and chain , chain wil break an valves get bend .
Other one is the streching of the chain , when that happens it wil eat up the theeth on the cam sprockets , and they wil fail at one point with same bend valves .
Inspect en in doubt change them .
Age is as much a factor or maybe even bigger , than mileage .