you cannot ceramic coat a catalytic converter.
coating the cat-back will have no real positive effect. the header is a different story. if it is done right, and you smooth out he insides of the tubes, and coat the header inside and out, you can gain some scavenging, which can increase power, though i have never seen it be more than a couple of horsepower on any engine. how much depends on cam timing, flow rates, the collector design, and the rest of the system design.
there are only 2 places in the country that i would trust to do the coating job. one (engineered applications) is here in los angeles. the other i think is in ohio, and i can't remember their name right now. they did the bearings on my engine though, and did a good job. i've also seen a header they did, and it was fine. you are looking at about $200, plus shipping. this does not include any of the internal prep work.
94 Midnight Metallic Blue Cab Porsche 968 w/deviating cashmere/black interior and WAY too many mods to list - thanks to eric for creating
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